General and Organic Chemistry - Chapter 8 - Acids and Bases

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What year and scientist proposed that acids and bases were defined by H+ and OH-
1884, Svante Arrhenius
What is Arrhenius definition of acids and bases?
Acid is a substance that produces H+ ions in an aqueous solution
and
Base is a substance that produces OH- ions in an aqueous solution
What do we know about water today in regards to a Arrhenius acid?
H+ reacts immediatley with water molecule to give a hydronium ion H3O+
What happens when HCl dissolved in water? Also show this with lewis a lewis structure.
Answer 4
H2O + HCl --> H3O+ + Cl-

the arrows show the change in position of electron pairs during the reaction; the first arrow shows the formation of an O-H bond, the second show the breaking of the H-Cl bond.
What are the slighly different things about a Arrhenius Base? Also show a lewis structure example.
Answer 5
Many bases are metal hydroixides such as KOH, NaOH, Mg(OH)2, and Ca(OH)2
These compounds are ionic solids and when they dissolve in water, their ions become hydrated and separate:
e.g NaOH(s) -H-2-O-> Na+(aq) + OH-(aq)
Not all bases are hydroxides; these bases produce OH- by reacting with water molecules
e.g.
NH3(aq) + H2O <--> NH4+(aq) + OH-
again curved arrows show the transfer of a proton from water to ammonia. The first arrow shows the formation of an N-H bond, the second shows breaking an H-O bond.
What is a strong Arrhenius Acid and what are 6 examples?
Strong acid is one that reacts completely or almost completely with water to form H3O+ ions
e.g.
Hydroiodic acid - HI
Hydrochloric acid - HCl
Sulfuric acid - H2SO4
Nitric acid - HNO3

??? Hydrobromic acid - HBr
??? Perchloric acid - HClO4
What is a strong Arrhenius Base and 3 examples.
Strong bases is one that reacts completely or almost completely with water to form OH- ions.
e.g.
Lithum hydroixde - LiOH
Sodium hydroxide - NaOH
Potassium hydroxide - KOH
Barium hydroxide - Ba(OH)2
What is a weak acid and a weak base, give examples of both. (Arrhenius)
A weat acid is a substance that dissociates only partially in water to produce H3O+ ions
e.g. acetic acid, is a weak acid; in water only 4 out of every 1000 molecules are converted to acetate ions

A weak base is a substance that dissociates only partially in water to produce OH- ions.
e.g. ammonia
Who is the scientist that we prodomently refer to when talking about acids and bases?
Bronsted-Lowry
What Bronsted-Lowry definition or and acid and base?
Acid is a proton donor
Base is a proton acceptor
What is an acid-base reaction?
A proton transfer reaction
What is a conjugated acid-base pair?
Answer 12
Any pair of molecules or ions that can be interconverted by transfer of a proton
Does the Bronsted-Lowry require water?
No it does not require water as a reactant
Lewis of a weak acid and a weak base.
Answer 14
What charges can acids and bases have?
An acid can be either, positive, neutral or negatively charge wereas a base is neutral or negatively charged.