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What 2 things will help a FF anticipate what a substance will do if it escapes from its container?
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State of matter
physical properties
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What is the difference between chemical and physical changes?
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Physical change is essentially a change of state.
Chemical change results in the alteration of the chemical nature of the material
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Boiling point definition
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Temperature at which a liquid will continually give off vapours in sustained amounts and if held at that temperature long enough will eventually turn completely into a gas
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What happens to a fuel when it surpasses its flash point?
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When the flashpoint is surpassed the fuel will give off sufficient vapour to support combustion ie the flame point
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LEL/LFL
UEL/UFL
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- A wide range tends to increase the danger of a material
- as a vapour cloud expands outward the liklihood of a flammable mixture increases
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What does vapour density tell us?
What are the lighter than air gases? HA HA MINCE
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Density of a gas relative to air assigned a value of 1 .: Tells us how a gas will stratify
Hydrogen
Ammonia
Helium
Acetylene
Methane
Illuminating gas (Neon, HCN)
Nitrogen
CO
Ethylene
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What is vapour pressure?
What are the various units of vapour pressure?
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Pertains to liquids
When in a closed container a certain amount of a liquid will vapourize to determine pressure in the container. = the pressure exerted by its vapour until the liquid and the vapour are in equilibrium
* relates to volatility
psi, atm, torr, mm Hg
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What 2 factors correlate to vapour pressure?
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Temperature of the materials
ambient temp
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Specific gravity of liquids
What are examples of substances <1 and >1
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Density of a liquid trelative to water (assigned value of 1)
H-Cs generally float on water = <1
carbon Disulfide = 2.6 specific gravity >1 .: sinks
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What is miscibility?
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Ability of chemicals to mix/dissolve
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Corrosivity definition
How does pH relate
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Ability of a material to cause damage, on contact, to skin, eyes, or other parts on the body ie destruction or irreversible damage
Acids pH= <7 bases pH=>7
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What tools do techs have to determine pH?
What must operations level consider with corrosives?
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More specialized ways of determining pH and may be a useful resource when handling corrosives
Materials are more complicated so responses are more complicated
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What must be considered when chemicals are burning?
Name some toxic byproducts:
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Nature of the fule will dictate the byproducts of combustion
Phosgene, cyanide, formaldehyde, oxides of nitrogen (nitric, nitrous and dioxide) lund irritants, CO
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What is ionizing radiation?
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Consists of energetic particles/waves that have the potential to ionize an atom or molecule through atomic reactions
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What is non-ionizing radiation?
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Refers to E-M radiation that does not carry enough energy to completely remove an electron from an atom or molecule.
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